A thrilling game saw both sides draw 3-3 at full-time leaving players having to line up for the dreaded penalty shoot-out to decide the victor.
One side representing England and another representing the rest of the world are set to kickoff at 8pm this evening.
England came out on top in the shootout with Inbetweeners star Blake Harrison converting the winning penalty.
Harrison, 32, posted a picture on Twitter of himself and actor David Harewood taken after the game, and wrote: "What a buzz!"
England had led 2-0 through Darren Bent and talent show contestant Jeremie Lynch before falling behind thanks to goals from Robbie Keane, Juan Sebastian Veron and Clarence Seedorf.
'I got to play against some seriously good footballers and scored the first penalty for the World XI, despite being robbed of my first goal.
In aid of global charity Unicef, two teams consisting of high-profile figures from various platforms will battle it out at Old Trafford.
'I would have loved to have headed home to Jamaica with the Soccer Aid for Unicef trophy under my arm, but my team and I are so proud to know that all of our hard work in training this week has meant that a record-breaking, life-changing amount of money was donated to Unicef tonight'.
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Sterling wage demands stall Man City contract talks
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Ranking the 5 teams most likely to win the 2019 NBA Finals
Durant said he wants people to realize that he gave it his all. "Sometimes you don't negotiate", Meyers said, via USA Today . Nothing to me was that, like, shocking but yeah we went through some stuff. "I never could have envisioned this".
Google Home can now handle three queries at once
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Why Alicia Silverstone's Son Tried to Make Out With Her
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